For all the flaws Spider-Man 3 has, so much of the marketing material surrounding it has stood the test of time for a reason. This poster and the one with the black suit mirrored in the window (and vice versa) are genuinely iconic pieces. You can hear that Christopher Young score just by looking at them.
From everything you've told me about Zack, this suits him all too perfectly. Definitely nailed that moody atmosphere you were going for with this one. Color me interested in seeing what you do next with your characters.